Principal Investigators:
Dr. Lizhi Xu (Assistant Professor, Department of Mechanical Engineering)
Dr. Yuan Lin (Associate Professor, Department of Mechanical Engineering)
This project is showcased as the Research Highlight (2023 September – October) in the third exhibition – Technology for Future in Innovation Wing Two
A new type of aerogels was successfully created using a self-assembled nanofiber network involving aramids, or Kevlar, a polymer material used in bullet-proof vests and helmets. Instead of using millimetre-scale Kevlar fibres, the research team used a solution-processing method to disperse the aramids into nanoscale fibrils. The interactions between the nanofibers and polyvinyl alcohol, another soft and “gluey” polymer, generated a 3D fibrillar network with high nodal connectivity and strong bonding between the nanofibers.
This composite nanofibre aerogel is a very strong and tough material that can withstand extensive mechanical loads, outperforming other aerogel material.
– High specific tensile modulus of ~625.3 MPa cm3 g−1;
– High fracture energy of ~4700 J m−2.
The nodal mechanics of fibrillar networks are essential to their overall mechanical behaviours. Our simulations revealed that the nodal connectivity and the bonding strength between the fibres influenced the mechanical strength of the network by many orders of magnitudes even with the same solid content
This aerogel with excellent mechanical properties can be used in wearable electronics, thermal stealth, filtration membranes, and other systems.
The mechanistic insights provide possibilities for the design of various nanofibrous materials.
Reference: He†, X. Wei†, Y. Lin*, L. Xu* et al. Nat. Commun.13, 4242 (2022)
Dr Yuan Lin (left) received the BS and MS degrees in Engineering Mechanics from Tsinghua University in 1999 and 2001, respectively. He later obtained a MS degree in Applied Mathematics in 2006 and followed by a Ph.D. degree in Solid Mechanics in 2007 from Brown University. He joined the Department of Mechanical Engineering in the University of Hong Kong in 2008 after serving a brief appointment at Brown University as a post-doctoral research associate. His research interests include cellular and molecular biomechanics, and mechanics of biological materials.
Dr Lizhi Xu (right) is currently an Assistant Professor at the Department of Mechanical Engineering, The University of Hong Kong. He obtained his B.S. degree (2009) in Applied Physics from Beihang University, and his Ph.D. degree (2014) in Materials Science and Engineering from University of Illinois, Urbana-Champaign. He worked as a postdoctoral research fellow at the University of Michigan from 2015 to 2018 before joining The University of Hong Kong. His research interests involve biomimetic materials, soft electronics, biomedical devices, and micro-/nanofabrication.
The press release article can be founded in HKU Press release (https://hku.hk/press/press-releases/detail/25120.html)
Aerogels are lightweight materials with extensive microscale pores, which could be used in thermal insulation, energy devices, aerospace structures, as well as emerging technologies of flexible electronics. However, traditional aerogels based on ceramics tend to be brittle, which limits their performance in load-bearing structures. Due to restrictions posed by their building blocks, recently developed classes of polymeric aerogels can only achieve high mechanical strength by sacrificing their structural porosity or lightweight characteristics.
A research team led by Dr Lizhi Xu and Dr Yuan Lin from the Department of Mechanical Engineering of the Faculty of Engineering of the University of Hong Kong (HKU), has developed a new type of polymer aerogel materials with vast applicational values for diverse functional devices.
In this study, a new type of aerogels was successfully created using a self-assembled nanofiber network involving aramids, or Kevlar, a polymer material used in bullet-proof vests and helmets. Instead of using millimetre-scale Kevlar fibres, the research team used a solution-processing method to disperse the aramids into nanoscale fibrils. The interactions between the nanofibers and polyvinyl alcohol, another soft and “gluey” polymer, generated a 3D fibrillar network with high nodal connectivity and strong bonding between the nanofibers. “It’s like a microscopic 3D truss network, and we managed to weld the trusses firmly together, resulting in a very strong and tough material that can withstand extensive mechanical loads, outperforming other aerogel materials,” said Dr Xu.
The team has also used theoretical simulations to explain the outstanding mechanical performance of the developed aerogels. “We constructed a variety of 3D network models in computer, which captured the essential characteristics of nanofibrillar aerogels,” said Dr Lin, who led the theoretical simulations of the research. “The nodal mechanics of fibrillar networks are essential to their overall mechanical behaviours. Our simulations revealed that the nodal connectivity and the bonding strength between the fibres influenced the mechanical strength of the network by many orders of magnitudes even with the same solid content,” said Dr Lin.
“The results are very exciting. We not only developed a new type of polymer aerogels with excellent mechanical properties but also provided insights for the design of various nanofibrous materials,” said Dr Xu, adding, “the simple fabrication processes for these aerogels also allow them to be used in various functional devices, such as wearable electronics, thermal stealth, filtration membranes, and other systems,”
The research was published in Nature Communications, in an article entitled “Ultrastrong and multifunctional aerogels with hyperconnective network of composite polymeric nanofibers”.
Link of the paper: https://www.nature.com/articles/s41467-022-31957-2